发布日期:2018-04-25 浏览次数:1617
PA has the following advantages and disadvantages in performance:
It is a crystalline material, and its advantages are as follows:
1. high mechanical strength, good toughness, high tensile strength
and compressive strength.
2. fatigue resistance is outstanding. It can maintain its original mechanical
strength after repeated bending.
4. corrosion resistance, alkali resistance and most salt solution, but also
weak acid, oil and gasoline.
6. the heat resistance is strong, the temperature range is wide, it can be used
for a long time at 45~100 C, and the heat resistance temperature is 120~150
C in a short time.
Processing requirements: generally, low molding temperature, low material
temperature, long time and high injection molding pressure should be taken.
The main varieties in PA are PA6 and PA66, which are dominant, followed by
PA11, PA12, PA610, PA 612, and PA1010, PA46, PA7, PA9, and PA13. Injection
molding (RIM) PA, aromatic PA, transparent PA, high impact (super toughened)
PA, electroplating PA, conductive PA, flame retardant PA, PA and other polymer
blends and alloys, etc., meet the special requirements, and are widely used as a
substitute for the traditional materials such as metal and wood as a variety of
structural materials.
PA is the most important engineering plastics and its output ranks first among
the five general engineering plastics.
Performance: PA is a tough angle translucent or milky white crystalline resin. As
engineering plastics, the molecular weight of PA is generally 15 thousand ~3. PA
has high mechanical strength, high softening point, heat resistance, low friction
coefficient, wear-resistance, self lubrication, vibration absorption and silencing, oil
resistance, weak acid, alkali resistance and general solvent, good electrical insulation
, non-toxic, odorless, good weatherability and poor dyeability. The disadvantage is
that the water absorbency is large, which affects the dimensional stability and
electrical properties. Fiber reinforcement can reduce the water absorption rate of
the resin and make it work under high temperature and high humidity. Nylon has
good affinity with glass fiber.
The hardness and rigidity of PA66 are the highest in PA, but the toughness is the
worst. All kinds of PA were classified according to their toughness size: PA66
< PA66/6 < PA6 < PA610 < PA11 < PA12.
The combustibility of PA is UL94 V-2, the limiting oxygen index is 24%~28%,
the decomposition temperature of PA is 299 degrees C, and spontaneous
combustion occurs at 449~499 C. The melt fluidity of PA is good, so the product
wall thickness can be as small as 1 mm.
It is widely used as a variety of mechanical and electrical parts, including bearings,
gear, pulley pump impeller, blade, high pressure seal ring, cushion, valve seat,
bushing, oil pipe, oil storage device, rope, belt, grinding wheel adhesive, battery
box, electric coil, cable joint and so on. There is also a considerable yield of
packaging tape, food film (low-temperature film for cooked food and cool drinks).
Several common PA flame retardants are halogen / antimony or other flame
retardant synergistic systems, red phosphorus or melamine type halogen free
flame retardant systems. From the perspective of quantity, halogen / antimony
synergy system is still the most widely used PA flame retardant system. In some
parts of Europe and Asia, efforts are being made to find alternatives to halogen
flame retardants. But generally speaking, these alternative systems usually have
problems of low thermal stability or moisture absorption. For red phosphorus,
there is also a problem of storage because it is inflammable. The following are the
main flame retardants used in nylon and their respective advantages and disadvantages.
1. halogen containing flame retardant system: the most important one of them
is the most widely used one in foreign countries is the brominated styrene polymer
, which has excellent thermal stability. And because it is mixed with PA, it has
good fluidity during the process. In addition, the flame-retardant PA prepared
by this method also has excellent electrical properties and better physical and
mechanical properties. The limitation of this flame retardant is poor optical
stability and is not completely compatible with PA. In addition, the cost is
higher than that of the ten brominated diphenyl ethers widely used in China.
Another kind of flame retardant used in PA for many years is the enemy
combustible. It is a kind of chlorine containing flame retardant with high flame
retardancy and electrical properties, but its limitation on thermal stability is only
suitable for the nylon flame retardant system with low processing temperature.
At present, the most widely used flame retardant in China is ten brominated
diphenyl ether. Because of its high bromine content, it has high flame retardant
efficiency to PA. It is the most economical flame retardant. But because it is
a filler type flame retardant, it has a great negative impact on the processing
fluidity and physical and mechanical properties of the product. In addition, its
thermal stability and light stability are also poorly differentiated. In recent
years, a new flame retardant used in the field of nylon flame retardancy has
been developed for ten brominated two benzoethane, which has the same
bromine content and high flame retardant efficiency as ten brominated diphenyl
ethers, and is the same as brominated styrene polymer without DPO
(called dioxin). In addition, it has good thermal stability and light stability. Its
limitation is that it is the same as ten brominated diphenyl ether as a filler
type flame retardant, which is poor in compatibility with the polymer, so the
processing fluidity and the physical and mechanical properties of the products
are poor. In addition, the cost is higher than that of ten brominated diphenyl ethers.
Guangzhou XiJia Chemical Co.,Ltd