发布日期:2018-04-17 浏览次数:1038
Flame-retardant ABS is made from YISHION ABS resin as base material, adding
high thermal stability flame retardant and so on. It is made by mixing, melting
and plasticizing and granulating. The preparation methods of flame retardant
ABS are usually divided into two types. One is copolymerization of monomers
containing halogen elements in graft polymerization, and then the flame retardant
ABS is prepared. This method is difficult to achieve satisfactory flame retardancy
because of the limitation of the amount of fourth monomers when copolymerization
. The two is to blend the compounds or polymers containing halogen elements and
other flame retardant additives and ABS resin to make blends of flame retardant ABS
, which has been widely used in industrial production. The flame retardant is easily
decomposed, carbonized or yellowing at high temperature, so the forming temper
ature should be as low as possible. It is usually set below 190 C (the resin melt
temperature is below 220 C). "Carbonization" is not bad, the flame retardancy
principle can be divided into four mechanisms: (1) isolation of oxygen and promoting
polymer carbonization to reduce flammable gas production and flame retardancy; (2)
produce non flammable gases to dilute oxygen concentration to slow combustion
speed; (3) heat absorption and release of water gas before the combustion occurs,
To reduce the temperature and achieve the effect of flame retardancy, (4) interfere
with the formation of free radicals by chemical methods. According to the composition,
the addition type flame retardants mainly include inorganic flame retardant, halogen
flame retardant (organic chloride and organic bromide), phosphorus flame retardant
, and phosphorous compound is a promising combustible in the global halogen free
combustible agent. Organic phosphate, such as BDP and RDP, is the main phosphorus
burning refractory in China. The refractory carbonization layer (char) is formed on the
plastic surface after the plastics are heated, and the carbonized layer obstruct the flow o
Guangzhou XiJia Chemical Co.,Ltd